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Domestic Solder Samples for Circuit Board Soldering to Improve PCBA Production Yield

Domestic Solder Samples for Circuit Board Soldering to Improve PCBA Production Yield

We conducted cross-line trials of JJY SN99.3CU0.7 lead-free solder on two main production lines. One line used the original imported material parameters of 235°C peak temperature + 60s time above liquidus, while the other re-calibrated the reflow oven temperature according to JJY's recommended 238°C + 55s parameters. The results showed that the latter reduced the average wetting angle by 2.1° on 0201 resistors and 0.4mm pitch QFNs, and the X-ray void area of BGA solder joints was reduced from 7.3% to 6.8%. Although this change is small, it was sufficient to reduce the AOI false positive rate by 11%. The production line also fine-tuned the stencil thickness from 0.12mm to 0.115mm, and reduced the squeegee pressure from 4.2kg to 3.8kg, which both prevented Solder Paste slump and ensured consistent solder volume for fine-pitch components.

Solder batch stability is key to the success or failure of the trials. We conducted melting point tests and Flux activity comparisons on three consecutive batches of JJY incoming materials. The solid-liquid interval width on the DSC curve was consistently controlled at 13.2±0.4°C, which fully matched the original production line control limits. Ion chromatography analysis of flux residues showed a Cl? content of 0.018μg/cm2, which is below the IPC-J-STD-004B Class L0 standard limit. More importantly, its viscosity decay rate after 45 minutes of stencil standing was only 4.7%, which is 1.9 percentage points lower than a previously used imported material. This is particularly practical for reducing mid-run stencil wiping frequency on dual-track high-speed printers.

After the reflow oven nitrogen purity was increased from 99.95% to 99.99%, the solder ball occurrence rate of JJY solder was reduced from 127 per million joints to 89, especially improving spherical residues at QFP pin roots. This is related to the higher thermal decomposition onset temperature of rosin derivatives in its flux, which must be supported by atmosphere cleanliness. We also found that when the PCB pad OSP film thickness fluctuation exceeded 0.3μm, JJY's wetting delay ability was slightly weaker than imported materials. Therefore, increasing the OSP supplier's CPK from 1.33 to 1.67 became a supporting action, otherwise local non-wetting is prone to occur on pads below 0.3mm.

All trial boards completed ICT+FCT functional testing before cross-section verification. A total of 1200 single boards were sampled, of which 89 had micro-voids that did not affect electrical performance. After excluding these 89 boards, the yield data was included in the statistics. The final PCBA first-pass yield was stable at 96.7%±0.3%, an increase of 4.4 percentage points compared to before the trial. Cold solder joint defects decreased by 52%, and the tombstoning rate was reduced from 0.18% to 0.07%. Bridging was concentrated in areas below 0.3mm pitch and was mostly related to uneven stencil tension, not the solder itself. JJY has since been included in the secondary qualified supplier list, and the temperature control accuracy of the solder paste refrigeration cabinet has been tightened from ±2°C to ±0.5°C to match its low-temperature sensitivity characteristics.

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