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Halogen-Free Solder Paste: Domestic Solder Paste Manufacturers Meeting ROHS Requirements

Halogen-Free Solder Paste: Domestic Solder Paste Manufacturers Meeting ROHS Requirements

After the production line switched in bulk last year to our JJY LFP-JJY5RQ-0307T4 halogen-free Solder Paste, the solder climbing defect rate for QFN0.4mm pitch devices was reduced from 0.82% to 0.07%. The root cause is that its ROL1-grade halogen control (single item <900ppm, combined items <1500ppm) and the T4 particle size distribution of the 0307 alloy powder synergistically reduce the interfacial oxide film resistance. Meanwhile, the rosin carrier volatilizes more thoroughly at a peak temperature of 245℃, avoiding the ionic residue micro-short circuits that conventional halogen-containing solder pastes tend to form under BGA packages.

For automotive lamp heat sink soldering scenarios, the LFP-JJY5RR-0307 zero-halogen solder paste stably controls the void rate within 3.2%. This is attributed to its 0ppm halogen specification combined with the eutectic properties of the 305 alloy powder, which increases the fluidity of molten metal by 17% during reflow and shortens bubble escape time by 0.8 seconds. The LFP-JJY5RNTT-305, also used on fingerprint lock motherboards, has a measured solder joint shear strength of 32.6N/mm2, 11% higher than conventional halogen-free solder pastes, due to its halogen content of only 100~200ppm and the addition of trace Bi/Ni modifiers.

After the water-washable LFP-JJY5RW1-0307 replaced imported materials at an LED bracket factory, it can still be cleaned thoroughly even when the conductivity of the cleaning water rises from 18.3μS/cm to 21.7μS/cm, indicating its extremely low ORH1-grade halogen release. The LFP-JJY5RG-In52Sn48 ultra-low temperature solder paste, used for soldering FPC reinforcement sheets on flexible displays, reduces stencil aperture clogging rate by 40% thanks to its 118℃ melting point paired with T7 powder, but it must be used in a reflow oven environment with nitrogen concentration >95% to prevent solder joints from turning gray.

The laser welding-specific LFP-JJY5RLJ-305, when dispensing on pneumatic valves, extends nozzle wear cycle to 280 hours due to the >92% sphericity of the T6 powder, and its <500ppm halogen content ensures a high pass rate for ionic migration tests on optical module lens brackets. In contrast, although the LFP-JJY2R-64351 medium-temperature solder paste is suitable for crystal oscillator soldering, the 151~172℃ melting range of the 64351 alloy makes it prone to solder bead spattering during the 205℃ soaking zone, so the squeegee pressure must be adjusted from 5.2kg to 4.8kg and the release speed reduced by 12% simultaneously.

During on-site commissioning of the aluminum-soldering-specific LFP-JJY5RW5-0307, it was found that cold solder joints on the aluminum nickel-plated layer easily occurred if the stencil aperture area ratio was maintained at 0.78. The yield only recovered from 89% to 99.6% after adjusting the ratio to 0.83, extending the post-printing standing time to 45 seconds, and raising the water wash tank temperature from 38℃ to 42℃. This shows that although the process window of Domestic Solder Pastes is now close to that of imported products, the stencil parameters, temperature zone settings, and cleaning conditions for each model must be recalibrated according to the alloy powder type and halogen grade, and old experience cannot be simply applied.

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